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A novel and convenient method for trifluoromethylation of organic halides using CF3SiR'3/KF/Cu(I) system

✍ Scribed by Hisao Urata; Takamasa Fuchikami


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
292 KB
Volume
32
Category
Article
ISSN
0040-4039

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Aryl iodides, vinyl bromides and tricarbonyl(chloroarene)chromium complexes react under mild conditions with sodium alkoxides and alkyl formates as source of carbon monoxide in the presence of dichlorobis(&iphenylphosphine)palladium as catalyst to give the corresponding carboxylic esters in high yie