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A novel and convenient method for palladium-catalysed alkoxycarbonylation of aryl and vinyl halides using HCO2R/NaOR system

✍ Scribed by Jean-François Carpentier; Yves Castanet; Jacques Brocard; André Mortreux; Francis Petit


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
271 KB
Volume
32
Category
Article
ISSN
0040-4039

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✦ Synopsis


Aryl iodides, vinyl bromides and tricarbonyl(chloroarene)chromium complexes react under mild conditions with sodium alkoxides and alkyl formates as source of carbon monoxide in the presence of dichlorobis(&iphenylphosphine)palladium as catalyst to give the corresponding carboxylic esters in high yields.


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