ChemInform Abstract: A Novel Allylic Hyd
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Toshiro Konoike; Yoshitaka Araki; Yasuhiko Kanda
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Article
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2010
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John Wiley and Sons
β 32 KB
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A Novel Allylic Hydroxylation of Sterically Hindered Olefins by Fe-Porphyrin-Catalyzed mCPBA Oxidation. -Triterpenes such as (I) bearing a sterically hindered olefin readily undergo a novel allylic hydroxylation by MCPBA in the presence of iron(III) tetrakis(pentafluorophenyl)porphyrin chloride as