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A novel allylic hydroxylation of sterically hindered olefins by Fe-porphyrin-catalyzed mCPBA oxidation

✍ Scribed by Toshiro Konoike; Yoshitaka Araki; Yasuhiko Kanda


Book ID
104262219
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
231 KB
Volume
40
Category
Article
ISSN
0040-4039

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ChemInform Abstract: A Novel Allylic Hyd
✍ Toshiro Konoike; Yoshitaka Araki; Yasuhiko Kanda πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

A Novel Allylic Hydroxylation of Sterically Hindered Olefins by Fe-Porphyrin-Catalyzed mCPBA Oxidation. -Triterpenes such as (I) bearing a sterically hindered olefin readily undergo a novel allylic hydroxylation by MCPBA in the presence of iron(III) tetrakis(pentafluorophenyl)porphyrin chloride as