A Novel (3,6,6)-Connected 3D Supramolecular Framework Constructed from 2D (4,4) Coordination Network [Pb(H2pimdc)2(H2O)2]n
✍ Scribed by Wang, Ni ;Li, Dong-Sheng ;Zhao, Jun ;Zhang, Peng ;He, Qiu-Fen ;Ke, Xi-Jun ;Li, Cai
- Book ID
- 115451424
- Publisher
- Taylor and Francis Group
- Year
- 2010
- Tongue
- English
- Weight
- 342 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0094-5714
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## Abstract A mixed‐valence copper(I,II) coordination polymer [Cu^I^~2~Cu^II^(4,4′‐bpy)~2~(pydc)~2~]·4H~2~O (4,4′‐bpy = 4,4′‐bipyridine and pydc = pyridine‐2,4‐dicarboxylate) featuring the “metal‐complex ligands” [Cu^II^(pydc)~2~]^2−^ was designed and synthesized hydrothermally from Cu(MeCO~2~)~2~,
The double-chain coordination polymer, {[Zn(H 2 O) 6 ][Zn(bbtc)H 2 O]•4H 2 O} n (bbtc = 3, 3 , 4, 4benzophenonetetracarboxylate), features two kinds of zinc center. One is octahedrally coordinated by six aqua ligands and the other is coordinated by four carboxylate oxygen atoms, derived from three b