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A novel (3+2) photocycloaddition of electron-deficient alkenes to diarylvinylidenecyclopropanes: regioselective formation of vinylidenecyclopentanes

✍ Scribed by Kazuhiko Mizuno; Hikaru Sugita; Takayoshi Hirai; Hajime Maeda; Yoshio Otsuji; Masahide Yasuda; Mitsuhiro Hashiguchi; Kensuke Shima

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
83 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

Irradiation of a benzene solution containing 1-diphenylvinylidene-2,2,3,3-tetramethylcyclopropane and an excess of acrylonitrile in the presence of Michler's ketone afforded 2-cyano-1-diphenylvinylidene-4,4,5,5-tetramethylcyclopentane in high yield.

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ChemInform Abstract: A Novel [3 + 2] Pho
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