ChemInform Abstract: A Novel Photocycloaddition of Allylic Silanes to 2,3-Dicyano-5,6- dimethylpyrazine: Formation of 2,8-Diazatricyclo(3.2.1.04,8)oct-2-ene Derivatives.
β Scribed by G. KONISHI; K. CHIYONOBU; A. SUGIMOTO; K. MIZUNO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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The chiral titanium complex, derived from TiCl 4 , Ti(O-iPr) 4 , and dioxole (+)-PPD, effectively promotes the enantioselective formation of compounds (III)/(VII) and (V)/(IX) in good yields and high e.e. from (E)-alkene (II) and benzoquinones (I) or (VI). Compounds (IV)/(VIII), which are also forme