A new ytterbium iodide mediated coupling of acyl cyanides and synthesis of 1,2-diketones
β Scribed by Promod Saikia; Dhrubojyoti D. Laskar; Dipak Prajapati; Jagir S. Sandhu
- Book ID
- 104252061
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 53 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Conversion of acyl cyanides 1 into 1,2-diketones 2 has been achieved by the action of ytterbium iodide in dry tetrahydrofuran at room temperature, in high yields.
π SIMILAR VOLUMES
The indium-mediated reductive coupling of acyl cyanides afforded the corresponding 1,2-diketones in moderate to good yields under neutral and mild conditions.
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