✦ LIBER ✦

A new two-fold interpenetrated three-dimensional compound based on metal–organic coordination polymers and {V4O12} clusters: [Cu(bipy)]4V4O12·2H2O (bipy=4,4′-bipyridine)

✍ Scribed by Chun-Dan Zhang; Shu-Xia Liu; Lin-Hua Xie; Bo Gao; Chun-Yan Sun; De-Hui Li

Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 203 KB
Volume: 753
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2005.05.041

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✦ Synopsis

A new composite material [Cu(bipy)] 4 V 4 O 12 $2H 2 O(bipyZ4,4 0 -bipyridine) (1) has been synthesized using hydrothermal technology. 1 is a two-fold interpenetrating three-dimensional structure composed of {V 4 O 12 } 4K rings covalently attached by four {Cu(bipy)} C moieties through the terminal oxo groups of vanadium sites. Compound 1 is the first example of interpenetrating (3,4)-connected network constructed from metal-organic polymers and polyoxometalates. Interestingly, Cu(I) atoms have a T configuration and {V 4 O 12 } 4K rings link to [{Cu(bipy)} C ] n chains via two different connecting behaviors.

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