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A new transient absorption spectrum observed in the flash photolysis of thiophene

✍ Scribed by S.L.N.G. Krishnamachari; T.V. Venkitachalam

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 218 KB
Volume: 55
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)85147-1

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✦ Synopsis

In the f&h photolysis of thiophene diluted with argon. a transient absorption spectrum in the region 3770 A to 4170 A has been observed_

The new absorption spectrum which consists of about 30 narrow and sharp red degraded bands could be analyzed into an electronic system with the origin band at 4113.8 A. The bands could be tentatively assigned to the C4H3 radical.

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