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A new total synthesis of pentenomycin

✍ Scribed by John K Gallos; Katerina C Damianou; Constantinos C Dellios

Book ID: 104231160
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 74 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01099-1

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✦ Synopsis

A new total synthesis of enantiomerically pure pentenomycin has been achieved by the intramolecular nitrone cycloaddition of the proper g-unsaturated aldehyde, easily accessible from L-arabinose, followed by reductive N O bond cleavage and further oxidative deamination of the resulting aminocyclopentitol.

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