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Stereoselective synthesis of (−)- and (+)-pentenomycins using RCM

✍ Scribed by G. Venkata Ramana; B. Venkateswara Rao

Book ID
104253817
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
157 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

An efficient synthesis of enantiopure (-)-and (+)-pentenomycins are described by reductive iodo elimination and ring-closing metathesis (RCM), as the key steps. The first synthesis of the unnatural (+)-isomer is described.

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First stereoselective total synthesis of
First stereoselective total synthesis of decarestrictine O via RCM protocol
✍ Palakodety Radha Krishna; T. Jagannadha Rao 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 290 KB

A convergent first stereoselective total synthesis of decarestrictine O via RCM protocol starting from 1,3propanediol and propylene oxide is reported.