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A new synthon for the regiospecific γ-alkylation of 2-cyclohexenones. Application to the synthesis of zingiberenol and oxygenated bicycle[3.3.1] nonanes

✍ Scribed by Leo A. Paquette; William A. Kinney

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 277 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86766-0

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✦ Synopsis

The regiospecific y-alkylation of y-sulfonylcyclohexenone ketals is described and applied to various synthetic objectives.

The utilitarian dienophilic properties of phenyl vinyl sulfoxidei and sulfone" in Diels-Alder reactions have recently been demonstrated in this laboratory. As part of this synthetic

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