A new synthesis of β-keto-phenylsulfoxides
✍ Scribed by Hugo J. Monteiro; João P. de Souza
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 135 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
A new synthetic route to &keto phosphonates from diethyl l-(trimethylsilyl)vinylphosphonate 1 is described. This involves nucleophilic addition of the oryanolithium reagents toward 1 followed by quenchiny with acid chlorides and alkyl isocyanates.
Electrochemical reduction of alicydic vinyl triflates (la -1 e) in a DMF solution containing 0.1 M Be4NIF 4 under an atmospheric pressure of cmbon dioxide with a platinum cathode and a magnesium anode resulted in the cleavage of an oxygen-sulfer bond of 1 to give the corresponding 15-keto cmboxylic