A straightforward three step route to (1S,2R)-and (1R,2R)-[2H]-glycerols la and lb is reported. The key asymmetric step involves an AD-mix-l~ dihydroxylation on deuterium labelled Z-and E-allyl benzoates 4a and 4b. The route should facilitate the use of [2H]-glycerols la-ld in high enantiomeric puri
β¦ LIBER β¦
A new synthesis of (R)- and (S)-2-2H-amino acids, including (R)- and (S)-2-2H1-glycine via stereochemically inert Co(III) complexes
β Scribed by Yu.N. Belokon; A.S. Melikyan; T.F. Salel'eva; V.I. Bakhmutov; S.V. Vitt; V.M. Belikov
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 805 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4020
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