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A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides

✍ Scribed by Samuel Braverman; Marina Cherkinsky


Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
217 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis


The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions.


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