A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides
✍ Scribed by Samuel Braverman; Marina Cherkinsky
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 217 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been found to undergo base-induced elimination of chloroform with formation of the corresponding N-sulfinylamines. Reaction proceeds smoothly under mild conditions.
📜 SIMILAR VOLUMES
A new method for the synthesis of thioaldehyde and thioketone S-oxides by an unusual base-induced I~-elimination of chloroform from readily available aUylic and bcnzylic trichloromethyl sulfoxides is described. The reaction proceeds smoothly under mild conditions. The facile preparation of cx,13-uns
## A new method for the synrhess of thioakiehyde S-oxides by base-induced elimination of chloroform from allyiic and benzylic trichloromethyl sulfoxides is described. The reaction proceed smoothly under mild conditions. A mechanic for this remarkable sulfine synthesis and apparently unprecedented j%