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A new 1,4-elimination of benzenesulfinic acid from β-keto phenylsulphones Via their tosylhydrazones

✍ Scribed by Roberto Ballini; Giovanna Bosica; Enrico Marcantoni

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
229 KB
Volume
52
Category
Article
ISSN
0040-4020

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A new synthesis of allylic alcohols or t
A new synthesis of allylic alcohols or their derivatives via reductive elimination from γ-phenylthio-β-nitroalcohols with tributyltinhydride
✍ Noboru Ono; Akio Kamimura; Aritsune Kaji 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 210 KB

Allylic alcohols are readily prepared by the Bu3SnH-promoted elimination reaction from y-phenylthio-8-nitroalcohls which are obtained by the joint reaction of nitroolefins, thiophenol, and aldehydes. In this paper we wish to report a new synthetic method of allylic alcohols or their derivatives (4\