✦ LIBER ✦
A new synthesis of allylic alcohols or their derivatives via reductive elimination from γ-phenylthio-β-nitroalcohols with tributyltinhydride
✍ Scribed by Noboru Ono; Akio Kamimura; Aritsune Kaji
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 210 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Allylic alcohols are readily prepared by the Bu3SnH-promoted elimination reaction from y-phenylthio-8-nitroalcohls which are obtained by the joint reaction of nitroolefins, thiophenol, and aldehydes.
In this paper we wish to report a new synthetic method of allylic alcohols or their derivatives (4_) starting from cr-nitro olefins (1). Our new method consists of two key steps, namely, one step-introduction of phenylthio and hydroxyalkyl groups into l_ by the joint reaction of three components (1,