then treated with petroleum ether. This affords 0.26g (32 %) ( 5 a ) , m.p. 293-294°C. 0.31 g (38%) ( 3 a ) can be obtained from the petroleum ether solution by distillation.
A new synthesis of amides from acyl fluorides and N-silylamines
✍ Scribed by Sundaramoorthi Rajeswari; Robert J. Jones; Michael P. Cava
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- French
- Weight
- 174 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Amide bonds are formed readily under mild conditions by the reaction of N-silylamines with the hydrolytically stable acyl fluorides.
📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract N,N‐Dialkylamides were chlorinated with oxalyl chloride and then allowed to react with LiAlHSeH to afford the corresponding N,N‐dialkyselenoamides in moderate to good yields. The N,N‐dialkylamides bearing bulky substituent groups were not converted into the corresponding selenoamides be