✦ LIBER ✦

A new synthesis of alkyl fluorides

✍ Scribed by Suzanne T. Purrington; James H. Pittman

Book ID: 104221775
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 96 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)88457-9

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✦ Synopsis

Reduction of a-fluorosulfides with sodium in alcohol results in the formation of fluoroalkanes. We recently reported a novel synthesis for a-fluorosulfides from thioacetals and mercuric fluoride in acetonitrile at room temperature.' Purification of the unstable a-fluorosulfides proved impossible, thus they were oxidized to the more stable a-fluorosulfoxides. After

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