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A new simple synthesis of 3,5-disubstituted 1-amino-1,3,5-triazine-2,4,6-triones from ethoxycarbonylhydrazones and isocyanates

✍ Scribed by François Chau; Jean-Claude Malanda; René Milcent


Publisher
Journal of Heterocyclic Chemistry
Year
1998
Tongue
English
Weight
174 KB
Volume
35
Category
Article
ISSN
0022-152X

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Synthesis of 3,5-disubstituted 1-amino-1
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A number of symmetrically 3,5-disubstituted 4-amino-1,2,4-triazoles have been prepared by the reaction of aromatic nitriles with hydrazine dihydrochloride or sulfate with an excess of hydrazine hydrate in ethylene or diethylene glycol under a nitrogen atmosphere. The structures of the new triazoles