A new simple synthesis of 3,5-disubstituted 1-amino-1,3,5-triazine-2,4,6-triones from ethoxycarbonylhydrazones and isocyanates
✍ Scribed by François Chau; Jean-Claude Malanda; René Milcent
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1998
- Tongue
- English
- Weight
- 174 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-152X
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## Abstract The 5‐aryl(or methyl)‐3‐phenylcarbamoyl‐1,3,4‐oxadiazol‐2(3__H__)‐ones 2, in the presence of sodium hydride in anhydrous dimethylformamide, were transformed into 1‐benzamido(or acetamido)‐3,5‐diphenyl‐1,3,5‐triazine‐2,4,6‐trione derivatives 7 in poor yields. However, compounds 7 were ob
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A number of symmetrically 3,5-disubstituted 4-amino-1,2,4-triazoles have been prepared by the reaction of aromatic nitriles with hydrazine dihydrochloride or sulfate with an excess of hydrazine hydrate in ethylene or diethylene glycol under a nitrogen atmosphere. The structures of the new triazoles