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A new route to hydride, carbonyl, and bis-dinitrogen complexes of tungsten

โœ Scribed by Bell, B.; Chatt, J.; Leigh, G. J.


Book ID
125330740
Publisher
Royal Society of Chemistry
Year
1970
Weight
134 KB
Volume
13
Category
Article
ISSN
0577-6171

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Catalytic Transformations of Vinylthiiranes by Tungsten Carbonyl Complexes. A New Route to 3,6-Dihydro-1,2-dithiins. -Two equivalents of vinylthiiranes (I) are transformed in the presence of W(CO) 5 (MeCN) catalyst to dithiins (II) and butadiene in good yields. Complexes W(CO) 4 (PPhR 2 )(MeCN) (R