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A New Route to Highly Conducting Polyenes

โœ Scribed by Prof. Henning Hopf; Cand.-Chem. Olaf Kretschmer; Dr. Herbert Naarmann


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
208 KB
Volume
28
Category
Article
ISSN
0044-8249

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A Streamlined Route to Highly Conjugated, all-(E) Polyenes Characteristic of Oxo Polyene Macrolide Antibiotics. -Couplings at the vinyl stannane end in the readily available organometallic linchpin (I) can be carried out with vinyl halides following two basic methods. The terminal acetylene in thes