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A New Route to Dihydrodithiins by a Catalytic Reaction of Vinylthiiranes with W(CO) 5 (NCMe)

โœ Scribed by Adams, Richard D.; Long, ; Perrin, Joseph L.

Book ID
120371181
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
73 KB
Volume
120
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Catalytic Transform
ChemInform Abstract: Catalytic Transformations of Vinylthiiranes by Tungsten Carbonyl Complexes. A New Route to 3,6-Dihydro-1,2-dithiins.
โœ Richard D. Adams; Joseph L. Perrin ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

Catalytic Transformations of Vinylthiiranes by Tungsten Carbonyl Complexes. A New Route to 3,6-Dihydro-1,2-dithiins. -Two equivalents of vinylthiiranes (I) are transformed in the presence of W(CO) 5 (MeCN) catalyst to dithiins (II) and butadiene in good yields. Complexes W(CO) 4 (PPhR 2 )(MeCN) (R