A new route to 1,4-disubstituted 5-thioxoperhydroimidazo[4,5-d]imidazol-2-ones
✍ Scribed by Jiřı́ Verner; Jan Taraba; Milan Potáček
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- French
- Weight
- 125 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
1,4-Disubstituted 5-thioxoperhydroimidazo [4,5-d]imidazol-2-ones were prepared by one-pot criss-cross cycloaddition reactions of 1,4-disubstituted 1,4-diazabuta-1,3-dienes with HNCS and HNCO generated in situ from potassium salts by acetic acid.
📜 SIMILAR VOLUMES
## Abstract magnified image A novel series of 2,4‐disubstituted‐1,2,4‐triazolo[1,5‐__a__]quinazolin‐5(4__H__)‐ones were prepared by Dimroth rearrangement of their respective isomers namely 1,4‐disubstituted‐[1,2,4]triazolo[4,3‐__a__]‐quinazolin‐5(4__H__)‐ones. The latter were prepared __via__ new
## Abstract The synthesis of imidazo[4,5‐__c__]pyrazol‐5‐ones (6) is reported. 5‐Amino‐4‐ethoxycarbonylaminopyra‐zoles 3a‐g when heated at 200° for 2 hours afford 6a‐g. In a similar manner imidazo[4,5‐__c__]pyrazol‐5‐one (6a) is readily obtained from 4‐amino‐5‐ethoxycarbonylaminopyrazole (5a).