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A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

✍ Scribed by Jonathan Axon; Laurent Boiteau; Jean Boivin; Judith E. Forbes; Samir Z. Zard


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
329 KB
Volume
35
Category
Article
ISSN
0040-4039

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The paper describes a new method of synthesizing biaryls and triaryls through an intramolecular ipso-substitution reaction initiated by the addition of an aryl radical to a benzyl ether. A tandem variant of the reaction has also been demonstrated. A short synthesis of isoaucuparin 27, a natural prod