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A New Planar Chiral Bisphosphine Ligand for Asymmetric Catalysis: Highly Enantioselective Hydrogenations under Mild Conditions

✍ Scribed by Pye, Philip J.; Rossen, Kai; Reamer, Robert A.; Tsou, Nancy N.; Volante, R. P.; Reider, Paul J.

Book ID: 118031588
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 152 KB
Volume: 119
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja970654g

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ChemInform Abstract: A New Planar Chiral

ChemInform Abstract: A New Planar Chiral Bisphosphine Ligand for Asymmetric Catalysis: Highly Enantioselective Hydrogenations under Mild Conditions.

✍ P. J. PYE; K. ROSSEN; R. A. REAMER; N. N. TSOU; R. P. VOLANTE; P. J. REIDER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

Mild Conditions. -A new chiral bis-phosphine ligand with a paracyclophane backbone is prepared and used as ligand in Rh-catalyzed hydrogenations of dehydroamino acid esters such as (I) with high enantioselectivity. -(PYE, P.