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A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids

✍ Scribed by Kinzel, Tom; Zhang, Yong; Buchwald, Stephen L.

Book ID
118157145
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
608 KB
Volume
132
Category
Article
ISSN
0002-7863

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A New Palladium Precatalyst Allows for t
A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids
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Boronic acids which quickly deboronate under basic conditions, such as polyfluorophenylboronic acid and fivemembered 2-heteroaromatic boronic acids, are especially challenging coupling partners for Suzuki-Miyaura reactions. Nevertheless, being able to use these substrates is highly desirable for a n

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## Abstract Polyfluorophenylboronic acid and five‐membered heteroaromatic boronic acids are used as coupling partners for Suzuki—Miyaura reactions in the presence of a newly developed precatalyst.

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v