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The synthesis and application of 2-acetyl-6-(1-naphthyl)-pyridine oxime as a new ligand for palladium precatalyst in Suzuki coupling reaction

✍ Scribed by Yongchang Zhou; Tatsuro Kijima; Taeko Izumi

Publisher: Journal of Heterocyclic Chemistry
Year: 2009
Tongue: English
Weight: 79 KB
Volume: 46
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.27

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✦ Synopsis

Abstract

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The synthesis of 2‐acetyl‐6‐(1‐naphthyl)‐pyridine oxime ligand from 2,6‐dibromopyridine and 1‐bromo‐naphthalene is described, and the new palladium(II) complex used as a Pd(0) precatalyst in the Suzuki cross‐coupling reaction was studied. The results showed that the novel naphthalene pyridine oxime complex could serve as an efficient precatalyst. J. Heterocyclic Chem., 46, 116 (2009).

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