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A new palladium-catalyzed synthesis of 1,2,3,4,4a,8b-hexahydro-1,4-methanobiphenylenes and 2-phenylbicyclo[2.2.1]hept-2-enes

✍ Scribed by Marta Catellani; Gian Paolo Chiusoli; Stefano Ricotti

Book ID: 103221550
Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 274 KB
Volume: 296
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(85)80360-0

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Swrmary: A new and highly stereoselective palladium-catalyzed synthesis is reported, based on two subsequent insertions of the bicycloE.2.gheptene system into an aryl or vinylpalladium bond, formed in situ from aryl or vinyl bromides. Recent papers on the synthesis of prostaglandin endoperoxide ana