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A new one-pot synthesis of silylated 1,3-dienes

✍ Scribed by Yanchang Shen; Tielin Wang

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
121 KB
Volume
31
Category
Article
ISSN
0040-4039

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Selenosulfonation of 1,3-dienes: One-pot
Selenosulfonation of 1,3-dienes: One-pot synthesis of 2-(phenylsulfonyl)-1,3-dienes
✍ Jan-E. BΓ€ckvall; Carmen NΓ‘jera; Miguel Yus πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 228 KB

A one-pot procedure for the transformation of a 1,3-diene into the corresponding 2-(phenylsulfonyl)-1,3-diene was developed. The reaction involves a 1,2-selenosulfonation-oxidation sequence. 2-( Phenylsulfonyl)-1,3-dienes have recently been shown to be versatile synthons in organic transformations.