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A new methylenecyclopropene synthesis and the isolation of a novel methylenecyclopropene dimer

✍ Scribed by W.E Billups; Christoph Gesenberg; Roger Cole

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
91 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The elimination of trimethylsilylbromide from either cis or trans-l-methylene-2-bromo-3trimethylsilylcyclopropane over solid cesium fluoride using the vacuum gas-solid reaction procedure yields methylenecyclopropene.

πŸ“œ SIMILAR VOLUMES

Synthesis and characterization of 1-chlo
Synthesis and characterization of 1-chloro-3-methylenecyclopropene
✍ Vladislav A. Litosh; Rajesh K. Saini; Andrew D. Daniels; W.E. Billups πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 155 KB

1-Chloro-3-methylenecyclopropene was prepared by vacuum gas-solid elimination of 2,2-dichloro-1-methylene-3-(trimethylsilyl)cyclopropane over solid cesium fluoride and characterized by 1H and 13C NMR spectroscopy at -103 Β°C.

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In light of the recent flurry of activity in the area of methylenecyclopropene syntheses, 2-6 we are prompted to report our work on a potentially simple approach to this general problem. This method is one that has been applied successfully to the analogous heptafulvene7 system and involves simply p