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The synthesis of a methylenecyclopropene (triafulvene) by proton abstraction from a cyclopropenyl cation

✍ Scribed by W.M. Jones; R. Scott Pyron

Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
233 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis

In light of the recent flurry of activity in the area of methylenecyclopropene syntheses, 2-6 we are prompted to report our work on a potentially simple approach to this general problem. This method is one that has been applied successfully to the analogous heptafulvene7 system and involves simply proton abstraction from the appropriate carbonium ion.

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