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A New Method of Transforming Esters of α -aminoacids into their Corresponding Isothiocyanates

✍ Scribed by Treat B. Johnson and Arthur A. Ticknor

Book ID
123665003
Publisher
National Academy of Sciences
Year
1917
Tongue
English
Weight
152 KB
Volume
3
Category
Article
ISSN
0027-8424

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A new oxidation process. Transformation
A new oxidation process. Transformation of gem-bishydroperoxides into esters
✍ Terent’ev, Alexander ;Platonov, Maxim ;Kutkin, Alexander 📂 Article 📅 2006 🏛 Walter de Gruyter GmbH 🌐 English ⚖ 193 KB

## Abstract A new oxidation process has been found where α,ω-dicarboxylic acid esters and ω-hydroxycarboxylic acid esters are formed on heating gem-bishydroperoxides in alcohol in the presence of BF3·Et2O. By addition of H2O2 to this reaction α,ω-dicarboxylic acid esters are formed almost selective