✦ LIBER ✦

A new oxidation process. Transformation of gem-bishydroperoxides into esters

✍ Scribed by Terent’ev, Alexander ;Platonov, Maxim ;Kutkin, Alexander

Book ID: 111487894
Publisher: Walter de Gruyter GmbH
Year: 2006
Tongue: English
Weight: 193 KB
Volume: 4
Category: Article
ISSN: 2391-5420
DOI: 10.2478/s11532-006-0012-6

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✦ Synopsis

Abstract

A new oxidation process has been found where α,ω-dicarboxylic acid esters and ω-hydroxycarboxylic acid esters are formed on heating gem-bishydroperoxides in alcohol in the presence of BF3·Et2O. By addition of H2O2 to this reaction α,ω-dicarboxylic acid esters are formed almost selectively.

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