A new method for the synthesis of thieno[2,3-c]pyrazoles
β Scribed by Zhongwen Wang; Zhengming Li; Jun Ren; Hansong Chen
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 124 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1042-7163
No coin nor oath required. For personal study only.
β¦ Synopsis
A new method has been found for the synthesis of pyrazoleacetate esters from pyrazolaldehyde. By a new tandem reaction, in which methyl 4pyrazoleacetate was reacted with carbon disulfide and iodomethane, thieno [2,3-c]pyrazole was synthesized. This was an easy method for the synthesis of this type of heterocycle.
π SIMILAR VOLUMES
## Abstract The complete manuscript of this communication appears in: __Angew. Chem. Suppl. 1982__, 1440. DOI:10.1002/anie.198214400
the solid compound occurred at 1686cm-1 and 1727cm-1 and before crystallisation (measured as film) at 1703 cm-1 and 1735 cm-1. Compounds IIIa-c were isolated by distillation at bath temperatures of 70-120Β°C and pressures of about 10-2mmHg.