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A new method for the synthesis of CF3-containing aminovinyl ketones

✍ Scribed by A. L. Krasovsky; V. G. Nenajdenko; E. S. Balenkova

Book ID
110316033
Publisher
Springer
Year
2001
Tongue
English
Weight
259 KB
Volume
50
Category
Article
ISSN
1573-9171

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We have recently reported' a method for the synthesis of u-substituted a,f? -unsaturated carbonyl compounds in which an oxalyl ketone or ester (1) is condensed with an aldehyde, JIJ generating a diketo lactone (z). Mild base cleavage then completes the synthesis.