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A new method for the synthesis of vinyl ketones

✍ Scribed by Gary M. Ksander; John E. McMurry


Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
146 KB
Volume
17
Category
Article
ISSN
0040-4039

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✦ Synopsis


We have recently reported' a method for the synthesis of u-substituted a,f? -unsaturated carbonyl compounds in which an oxalyl ketone or ester (1) is condensed with an aldehyde, JIJ generating a diketo lactone (z). Mild base cleavage then completes the synthesis.


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