A new method for the synthesis of acylsilanes via one-carbon homologation of aldehydes
โ Scribed by Yoshida, Junichi; Matsunaga, Shinichiro; Ishichi, Yuji; Maekawa, Tsuyoshi; Isoe, Sachihiko
- Book ID
- 126858606
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 481 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
\_ Thiiranes are useful precursors for the synthesis of olefins by phosphlne la or phosphltelb'c mediated desulfurizations. However, these heterocycles are obtained from multi-step procedures involving intermediate oxiranes2 derived from carbonyl compounds or olefins. The synthetic utility of oxazol
l'he synthesis of (z, &unsaturated aldehydes has been a focus of current interest'. However there are only few methods for the syntheses of a, B-unsaturated aldehydes hy one-carbon homclogation'. We wish to report a convenient synthesis of the 1-alkenecarboxaldehydes from the corresponding carbonyl