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A New Method For The Generation of Nitriles From Aldoximes

✍ Scribed by Jose, Binoy; Sulatha, M. S.; Pillai, P. Madhavan; Prathapan, Sreedharan

Book ID
120418841
Publisher
Taylor and Francis Group
Year
2000
Tongue
English
Weight
211 KB
Volume
30
Category
Article
ISSN
0039-7911

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πŸ“œ SIMILAR VOLUMES

New method of in situ generation of nitr
New method of in situ generation of nitrile oxides by MnO2 oxidation of aldoximes
✍ JarosΕ‚aw Kiegiel; Magdalena PopΕ‚awska; Julita JΓ³ΕΊwik; MaΕ‚gorzata Kosior; Janusz πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 197 KB

Manganese(IV) oxide (MnO~\_) was found to oxidize aldoximes to nitrile oxides. Nitrile oxides were trapped in situ with dipolarophiles to furnish 2-oxazolines, The best results were obtained with hydroximinoacetates as nitrile oxide precursors.