𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new method for the formation of the α-glycoside bond of sialyl conjugates based on long-range participation

✍ Scribed by Takashi Takahashi; Hirokazu Tsukamoto; Haruo Yamada

Book ID
104258273
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
223 KB
Volume
38
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Glycosidation of N-acetylneuraminic acid with primary and secondary alcohols in acetonitrile or DME utilizing "long range participation" produced the aglycosyl linkages with high stereoselectivity.

📜 SIMILAR VOLUMES

A method for the one-pot regioselective
A method for the one-pot regioselective formation of the two disulfide bonds of α-conotoxin SI
✍ Alan Cuthbertson; Bård Indrevoll 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 78 KB

A one-pot method for the regioselective formation of the disulfide bridges of α-conotoxin SI employing temperature-controlled orthogonal protecting groups is reported. The pairing of t-butyl and 4-methylbenzyl sidechain protecting groups was chosen for the four cysteine residues. Cleavage of the pep