The first synthesis of a water-soluble cationic sugar-substituted arene rhodium complex has been described. The w Ž . x water-soluble cationic rhodium complex was synthesized by the reaction of an ethanol solution of Rh COD Cl with 2 AgBF and then with phenyl-b-D-glucopyranoside. This water-soluble
✦ LIBER ✦
A new, highly selective, water-soluble rhodium catalyst for methyl acrylate hydroformylation
✍ Scribed by Georges Fremy; Yves Castanet; Ryszard Grzybek; Eric Monflier; André Mortreux; Anna M. Trzeciak; Jozef J. Ziolkowski
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 500 KB
- Volume
- 505
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The methylated cyclodextrins/__m__‐TPPTC [tris(__m__‐carboxyphenyl)phosphane trilithium salt] couples proved to be more efficient than the well‐known methylated cyclodextrins/TPPTS [tris(__m__‐sulfonatophenyl)phosphane trisodium salt] systems in terms of activities and selectivities to