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A new generation of giant analogs of tetrathiafulvalene (TTF): Vinylogs of TTF bearing four 1,4-dithiafulvalenyl substituents

โœ Scribed by Belyasmine, A.; Gorgues, A.; Jubault, M.; Duguay, G.


Book ID
122489658
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
127 KB
Volume
42
Category
Article
ISSN
0379-6779

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Tetrathiafulvalene (TTF) fused to acenap
โœ Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A.K. Howard ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

The reaction of transient 1,3-dithiole-2,4,5-trithioue 4 with acenaphthylene afforded the Diels-Alder adduct 5, which was dehydrogenated to yield 6; cross-coupling of 6 with 7 gave the tetrathiafulvalene (TIT) derivative 8, which was converted into the di(methylsulfanyl) analogue 10, the solution el