𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new, general route to 1-chloro-1-ethynylcyclopropanes via chloro(trimethylsilylethynyl)carbene

✍ Scribed by Konstantin N. Shavrin; Irina V. Krylova; Inna B. Shvedova; Oleg M. Nefedov


Book ID
111729994
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
110 KB
Volume
7
Category
Article
ISSN
0959-9436

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


1-chloro-1H-phosphirenes - a new synthes
✍ Werner Schnurr; Manfred Regitz πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 268 KB

The chlorocarbenes 2, generated thermally from the diazirines 8, take part in [2 + I]-cycloaddition reactions with the phosphaalkenes 5 to furnish the dichlorophosphiranes 9. At 130 'C, the latter products 9 undergo elimination of chlorotrimethylsilane to form the 1-chloro-lH-phosphirenes 4. -While