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1-chloro-1H-phosphirenes - a new synthesis from phosphaalkenes and carbenes

✍ Scribed by Werner Schnurr; Manfred Regitz

Book ID: 104229445
Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 268 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)99292-x

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✦ Synopsis

The chlorocarbenes 2, generated thermally from the diazirines 8, take part in [2 + I]-cycloaddition reactions with the phosphaalkenes 5 to furnish the dichlorophosphiranes 9. At 130 'C, the latter products 9 undergo elimination of chlorotrimethylsilane to form the 1-chloro-lH-phosphirenes 4. -While l-alkyl-2 or 1-aryl-lH-phosphirenes have been known for some years ,

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