A New Family of Biisoquinoline Chelates
β Scribed by Fabien Durola; David Hanss; Pirmin Roesel; Jean-Pierre Sauvage; Oliver S. Wenger
- Book ID
- 102171496
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 214 KB
- Volume
- 2007
- Category
- Article
- ISSN
- 1434-193X
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## Abstract The macrocyclic biisoquinoline **14** was synthesized in just four preparative steps starting from the simple biscarboxaldehyde **8**. The interaction with camphorsulfonic acid induces an acidβcatalyzed partial deracemization.
Bromo and chloro polyumnes react mth tnmethylsllylacetylene in the presence of Pd(PPh3)#12 / CuI and dusopropylamme to pve new substituted polylmlnes la to 8a These compounds are deprotected mth K$Oa m MeOH / THF to produce the
0 S.M. ATLAS AND Ii. F. 3lhtttc, nngew. Chcm., 72 (1960) 249. 7 I-I. FXEDLISR,J. Pmkl. Clhm.. [4] 13 (1901) 77. 8 I<. W. G. HOLLINGSHDAV, Oxinc rrttd its Derivatives, Uutterworths, London, 1954. \* This work is abstrnctcd from a dissertation submitted to the Craduntc School, Khivcrsity of Connecticu