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A new family of (arene)osmium(0) and -osmium(II) complexes

✍ Scribed by Stahl, Stefan; Werner, Helmut


Book ID
120090867
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
877 KB
Volume
9
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES


Osmium(II) and Ruthenium(II) Arene Malto
✍ Annaβ€…F.β€…A. Peacock; Michael Melchart; Robertβ€…J. Deeth; Abraha Habtemariam; Simon πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 475 KB

## Abstract Density functional calculations show that aquation of [Os(Ξ·^6^‐arene)(XY)Cl]^__n__+^ complexes is more facile for complexes in which XY=an anionic O,O‐chelated ligand compared to a neutral N,N‐chelated ligand, and the mechanism more dissociative in character. The O,O‐chelated XY=maltola