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Highly Antiproliferative Ruthenium(II) and Osmium(II) Arene Complexes with Paullone-Derived Ligands

✍ Scribed by Schmid, Wolfgang F.; John, Roland O.; Arion, Vladimir B.; Jakupec, Michael A.; Keppler, Bernhard K.


Book ID
121001645
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
219 KB
Volume
26
Category
Article
ISSN
0276-7333

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Osmium(II) and Ruthenium(II) Arene Malto
✍ Anna F. A. Peacock; Michael Melchart; Robert J. Deeth; Abraha Habtemariam; Simon 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 475 KB

## Abstract Density functional calculations show that aquation of [Os(η^6^‐arene)(XY)Cl]^__n__+^ complexes is more facile for complexes in which XY=an anionic O,O‐chelated ligand compared to a neutral N,N‐chelated ligand, and the mechanism more dissociative in character. The O,O‐chelated XY=maltola