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A new facile preparation of a bifunctionalized C6 homologating agent from 1,4-cyclohexadiene

✍ Scribed by Sabine Michaud; Jacques Viala

Book ID: 104209268
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 434 KB
Volume: 55
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(99)00077-0

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✦ Synopsis

a new preparation of the bifunctionalized unsaturated C6 homologating agent 2b which is an efficient synthetic tool is described. This method is atom economic, very efficient on grams scale and easy to handle from cheap commercially available 1,4-cyclohexadiene. Synthetic applications by using a mild and selective monohydrolysis of acetal catalysed by FeCI3 are described.

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