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A new diospyrol glycoside from Diospyros mollis Griff.

โœ Scribed by Somboun Paphassarang; Michel Becchi; Jean Raynaud

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
187 KB
Volume
25
Category
Article
ISSN
0040-4039

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Diospyrol 4 is constructed from a masked butadiene synthon. anthracene adduct 1 [R = H]. The key construction steps comprise tandem Michael addition-Dieckmann condensations, first between anion 7 and 1 , and subsequently between anion 7 and 15. ln the previous communication 1 we described a straigh