𝔖 Bobbio Scriptorium
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A NEW CYCLIZATION REACTION 1

✍ Scribed by Bradsher, Charles K.; Beavers, Dorothy J.; Little, Edwin D.


Book ID
126491310
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
147 KB
Volume
76
Category
Article
ISSN
0002-7863

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A/~trac~ A new type of anionic Β’yelization has been discovered in which the condensation of alkyl benzoates with simple nitriles, induced by an excess of LDA, leads directly to substituted-3-amino-2-indan-l-ones. The corresponding intermediL.t,~-[~-oxmitriles undergo cyclization to give, in most ins